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Mendeleev · Isotope

Helium-4

Helium-4: atomic number 2, mass number 4, with 2 protons and 2 neutrons.

IsotopeHe
42He
Protons2
Neutrons2
Electrons (neutral)2

The proton count fixes the element: 2 protons identify Helium. Mass number 4 is the total number of protons and neutrons.

A neutral Helium-4 atom also has 2 electrons. Changing neutrons changes the isotope; changing electrons changes the charge.