What happens
An electrolytic cell has two electrodes and an electrolyte that carries ions. An external power source forces electron flow while oxidation and reduction occur at different electrodes.
Where do we see it?
Water electrolysis is a familiar example: overall, water is converted into hydrogen and oxygen. The detailed reactions depend on the electrolyte and membrane used.
Electrolysis is also used to refine metals, apply metal coatings and manufacture important chemicals.
A little further
The electrical energy is not just a trigger. It supplies the energy needed to push the system along a chemical path that would not proceed that way spontaneously.