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Mendeleev / Compounds / Calcium hydroxide
Ionic solid · strong base

Calcium hydroxide

Ca(OH)₂

Calcium hydroxide is Ca(OH)₂, an ionic solid composed of Ca²⁺ and OH⁻ ions. Two hydroxide ions are required to balance each calcium ion.

Material distinction: limewater is an aqueous solution of calcium hydroxide; slaked lime is solid calcium hydroxide material. Neither term changes the underlying compound identity.
Essentials

Ca(OH)₂ is one Ca²⁺ plus two OH⁻ ions.

The parentheses matter: the subscript 2 applies to the entire hydroxide ion, not only to oxygen.

Calcium two plus and two hydroxide ions shown as the components of calcium hydroxide
Beginner view: one +2 cation requires two −1 anions.
Formula reading

Ca(OH)₂ contains two oxygens and two hydrogens.

The OH group is a polyatomic ion that must be counted as a unit.

Detail

Calcium hydroxide is only moderately soluble, but the dissolved portion dissociates into ions.

A saturated solution contains solvated Ca²⁺ and OH⁻ in equilibrium with undissolved solid. Strong-base behavior refers to the hydroxide ions present in solution, not to unlimited solubility.

Calcium hydroxide solid in equilibrium with calcium and hydroxide ions in water
Detail view: solubility and ionic dissociation are separate ideas.
Strong base ≠ highly soluble

A compound can produce strongly basic dissolved ions without dissolving without limit.

Solubility controls how much enters solution; acid–base strength describes the behavior of the dissolved species.

Read the formula

CaO2H2 is a compact statement of composition.

Subscripts count atoms in the chemical formula unit. Atom percentages and mass percentages answer different questions because the constituent elements have different atomic masses.

1 Cacalcium atom
2 Ooxygen atoms
2 Hhydrogen atoms

Percentages are calculated from standard relative atomic masses and rounded for display.

Understand

Hydroxide is the reactive base in neutralization.

In aqueous acid–base chemistry, spectator ions can be omitted so the central change is H₃O⁺ reacting with OH⁻ to make water.

Hydronium plus hydroxide gives water
Net ionic equation for neutralization.
Carbon dioxide link

Calcium hydroxide can also react with CO₂ to form calcium carbonate.

This links the calcium hydroxide and calcium carbonate pages through a familiar precipitation/carbonation process.

Reference identifiers

Names and identifiers that pin down the chemical identity.

FormulaCa(OH)₂
CAS Registry Number1305-62-0
Common material nameslaked lime
Advanced

Push past the first model without losing the simple picture.

Is Ca(OH)₂ a molecule?

No. The solid is ionic; Ca(OH)₂ is a formula unit.

Why can a sparingly soluble solid still make a basic solution?

The fraction that dissolves supplies OH⁻ ions, and those ions strongly affect pH.

Is limewater pure liquid calcium hydroxide?

No. Limewater is an aqueous solution containing dissolved calcium hydroxide species.

Constituent elements

Connect the compound back to the periodic table.