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Molecular oxide · one-carbon compound

Carbon dioxide

CO₂

Carbon dioxide is a molecular compound containing one carbon atom and two oxygen atoms. Its O=C=O skeleton is linear. Each C=O bond is polar, but the two bond-dipole contributions oppose one another exactly in the ideal linear molecule, so CO₂ has no permanent molecular dipole.

Everyday distinction: carbon dioxide gas, dissolved CO₂ and solid CO₂ (“dry ice”) are the same chemical substance in different physical environments; carbonic acid H₂CO₃ is a different species formed only from a fraction of dissolved CO₂.
Essentials

The first fact to see: CO₂ is linear.

One carbon atom lies between two oxygen atoms. For a first reading, that straight O=C=O arrangement is more important than any numerical angle or dipole notation.

Simple linear O=C=O molecule without angle or dipole labels
Beginner view: carbon dioxide is a straight, symmetric molecule.
Why shape matters

Linear symmetry changes the molecular polarity.

Each C=O bond is polar, but the molecule has two equivalent bonds pointing in opposite directions. Their dipole contributions cancel when the geometry is perfectly linear and symmetric.

Geometry in detail

O–C–O is 180°: the two bond dipoles cancel by symmetry.

The 180° angle describes the linear molecular geometry. The molecule has polar bonds but no permanent molecular dipole because the two equal bond-dipole vectors are opposite.

Linear carbon dioxide with a 180 degree O-C-O angle and two equal opposite bond dipoles
Detailed view: the arrows describe bond-dipole directions; their vector sum is zero for the symmetric linear molecule.
Key distinction

Bond polarity ≠ molecular polarity.

A bond describes unequal electron sharing between two atoms. Molecular polarity depends on the vector sum of all bond dipoles and therefore on geometry as well as bond polarity.

Read the formula

CO₂ is a compact statement of composition.

One carbon atom is paired with two oxygen atoms in each molecule. The formula gives composition; the O=C=O structural formula adds connectivity and bond multiplicity.

1 Ccarbon atom
2 Ooxygen atoms

Percentages by mass use standard atomic-weight values and are rounded for display.

CO₂ in water

Dissolved carbon dioxide is not identical to carbonic acid.

CO₂ can dissolve physically in water. A smaller fraction reacts with water to form carbonic acid, and carbonic acid can participate in acid–base equilibria. Writing every dissolved CO₂ molecule as H₂CO₃ overstates the extent of hydration.

CO₂(aq) + H₂O ⇌ H₂CO₃ ⇌ HCO₃⁻ + H⁺

This compact sequence shows chemical relationships, not equal concentrations of all species.

Vibrational chemistry

A molecule can have no permanent dipole and still absorb infrared radiation.

CO₂ has vibrational modes that temporarily change its dipole distribution. Its asymmetric stretch and bending vibrations are infrared-active; the perfectly symmetric stretch does not create the same changing dipole. This distinction matters in spectroscopy and atmospheric physics.

Advanced

Symmetry explains more than the shape.

Why is CO₂ linear?

At carbon, the two C=O bonding directions arrange opposite one another in the equilibrium molecule. In valence-bond shorthand this is often described with sp hybridisation; molecular-orbital descriptions reach the same observed linear geometry without requiring hybrid orbitals as physical objects.

Does “non-polar” mean CO₂ cannot interact with electric fields?

No. Zero permanent dipole is not zero polarizability. An external field can distort the electron distribution and induce a dipole.

Is dry ice made of a different molecule?

No. Solid carbon dioxide contains CO₂ molecular units packed in a crystal. Sublimation changes the physical state, not the molecular formula.

Reference identity

Carbon dioxide as a chemical substance.

Molecular formulaCO₂
Molar mass44.0095 g/mol
CAS Registry Number124-38-9
PubChem CID280
Standard InChIInChI=1S/CO2/c2-1-3
Equilibrium molecular geometryLinear O=C=O; 180°
Related

Use CO₂ to connect atomic properties, geometry and acid–base chemistry.