Mendeleev · guide page

How to read the periodic table

An element cell tells you which element you are looking at. Its row, column and block then tell you how its outer electrons are organised and give useful clues about its chemistry. The aim is to read the table as a map of atomic structure, not as a list of facts to memorise.

1 · Read one cell

Start with the atomic number

The atomic number Z is the number of protons in the nucleus. It identifies the element: Z = 11 means sodium, whether you are looking at a particular isotope or an ion. Na is sodium's chemical symbol. The decimal value shown in many tables is a relative atomic-mass value; it is not the atomic number and it is not the mass number of one isotope.

Why this mattersFor a neutral sodium atom, Z = 11 also means 11 electrons. That gives the starting point for its electron configuration: 1s² 2s² 2p⁶ 3s¹.

Common mistake: 22.990 does not mean “22.990 protons plus neutrons”. A periodic-table cell combines several kinds of information, so identify what each number represents before using it.

11 atomic number
Na
Sodium
22.990 relative atomic mass
Z · atomic numberNa · symbolSodium · name22.990 · relative atomic mass
2 · Find the position

Group means column; period means row

The groups are the vertical columns numbered 1 to 18. Elements in the same group often have related outer-electron structures, which is why their chemistry can show recurring patterns. The periods are the horizontal rows numbered 1 to 7. Across a period, atomic number rises by one from one element to the next.

Use the buttons on the map. They highlight group 1, period 3, or the electronic blocks so the structure becomes visible rather than abstract.

Predict before you clickNa and K should line up in the same column. Na and Cl should sit on the same row.
1H2He 3Li4Be5B6C7N8O9F10Ne 11Na12Mg13Al14Si15P16S17Cl18Ar 19K20Ca21Sc22Ti23V24Cr25Mn26Fe27Co28Ni29Cu30Zn31Ga32Ge33As34Se35Br36Kr

Group 1: Li, Na and K line up vertically. Their outer ns¹ configuration helps explain several chemical similarities.

3 · The blocks

Why are the blocks 2, 6, 10 and 14 columns wide?

The letters s, p, d and f refer to electron subshells. An s subshell contains 1 orbital, p contains 3, d contains 5 and f contains 7. Each orbital can hold at most two electrons, giving capacities of 2, 6, 10 and 14 electrons.

An orbital is not a tiny circular path. It is a quantum state associated with a probability distribution in space.

Reading sodiumIts configuration ends in 3s¹. The differentiating electron occupies an s subshell, so sodium belongs to the s block.
s1 orbital · 2 e⁻
d5 orbitals · 10 e⁻
p3 orbitals · 6 e⁻
f7 orbitals · 14 e⁻ · usually drawn below the main table
4 · Guided example

Read sodium from its cell to its chemistry

① Z = 11

11 protons; 11 electrons if the atom is neutral.

② Period 3

The highest occupied principal shell in the ground state is n = 3.

③ Group 1

Its outer configuration follows the ns¹ pattern.

NaMgAlSiPSClAr

Configuration: 1s² 2s² 2p⁶ 3s¹ = [Ne] 3s¹. Losing that single 3s electron produces Na⁺, which is why +1 is overwhelmingly common for sodium. The table is useful because position and electron configuration tell the same structural story.

Nuance: group, period and block give patterns and tendencies. For a precise quantitative property—atomic radius, ionisation energy or electronegativity—use the relevant definition and data rather than treating position alone as a measurement.
5 · Put it into practice

Your turn: read chlorine

Chlorine has Z = 17 and lies in period 3, group 17, p block.

1 · How many protons and electrons does neutral Cl have?

Answer: 17 protons and 17 electrons.

Why: atomic number counts protons, and a neutral atom has the same number of electrons as protons.

Method: start from Z. Only change the electron count if the species carries a charge.

2 · What outer-electron configuration should you expect?

Answer: [Ne] 3s² 3p⁵, giving seven valence electrons in the usual main-group count.

Why: period 3 identifies the outer principal shell, group 17 points to the seven-electron valence pattern, and the p block tells you that the p subshell is being filled.

Check: one more electron gives the argon-like configuration [Ar], which helps explain why Cl⁻ is common.

Use the map carefully

A powerful summary, not an answer to every question

The periodic table compresses atomic number, electron structure and recurring chemical patterns into one layout. It helps you predict broad behaviour, compare neighbours and choose the right model. It does not directly tell you everything about reactivity, toxicity, phase, melting point or the properties of a compound. Those questions need additional data and context.